全文获取类型
收费全文 | 1042篇 |
免费 | 31篇 |
国内免费 | 1篇 |
专业分类
化学 | 816篇 |
晶体学 | 16篇 |
力学 | 9篇 |
数学 | 54篇 |
物理学 | 179篇 |
出版年
2022年 | 5篇 |
2021年 | 9篇 |
2020年 | 10篇 |
2019年 | 9篇 |
2018年 | 7篇 |
2017年 | 10篇 |
2016年 | 13篇 |
2015年 | 21篇 |
2014年 | 20篇 |
2013年 | 48篇 |
2012年 | 30篇 |
2011年 | 40篇 |
2010年 | 48篇 |
2009年 | 37篇 |
2008年 | 81篇 |
2007年 | 63篇 |
2006年 | 67篇 |
2005年 | 53篇 |
2004年 | 78篇 |
2003年 | 58篇 |
2002年 | 74篇 |
2001年 | 13篇 |
2000年 | 18篇 |
1999年 | 8篇 |
1998年 | 5篇 |
1997年 | 10篇 |
1996年 | 14篇 |
1995年 | 7篇 |
1994年 | 9篇 |
1993年 | 8篇 |
1992年 | 9篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 7篇 |
1988年 | 7篇 |
1986年 | 11篇 |
1985年 | 19篇 |
1984年 | 17篇 |
1983年 | 7篇 |
1982年 | 18篇 |
1981年 | 9篇 |
1980年 | 8篇 |
1979年 | 8篇 |
1978年 | 8篇 |
1977年 | 7篇 |
1976年 | 11篇 |
1973年 | 13篇 |
1969年 | 4篇 |
1968年 | 5篇 |
1967年 | 3篇 |
排序方式: 共有1074条查询结果,搜索用时 31 毫秒
41.
Guo‐Qing Bian Takayoshi Kuroda‐Sowa Hisashi Konaka Masahiko Maekawa Megumu Munakata 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(7):m338-m340
The title compound, [Mn2(μ‐O)(C6H3NO3)2(C5H5N)4]·H2O, was isolated from the reaction of 2,6‐pyridinedicarboxylic acid with [Mn12O12(CH3COO)16(H2O)4] in pyridine. The dimanganese complex has twofold symmetry; the MnIII atoms are bridged by one oxo and two amidate ligands and show compressed octahedral Jahn–Teller distortion. The molecular packing comprises a three‐dimensional structure constructed by means of extensive intermolecular interactions, including three kinds of hydrogen bonds and π–π interactions. 相似文献
42.
Tungsten‐Catalyzed Regio‐ and Enantioselective Aminolysis of trans‐2,3‐Epoxy Alcohols: An Entry to Virtually Enantiopure Amino Alcohols 下载免费PDF全文
Dr. Chuan Wang Prof. Dr. Hisashi Yamamoto 《Angewandte Chemie (International ed. in English)》2014,53(50):13920-13923
The first catalytic enantioselective aminolysis of trans‐2,3‐epoxy alcohols has been accomplished. This stereospecific ring‐opening process was efficiently promoted by a tungsten/bis(hydroxamic acid) catalytic system, furnishing various anti‐3‐amino‐1,2‐diols with excellent regiocontrol and high enantioselectivities (up to 95 % ee). Moreover, virtually enantiopure 3‐amino‐1,2‐diols could be obtained by the sequential combination of two reactions that both involve the use of a chiral catalyst. 相似文献
43.
44.
45.
46.
Ryohei Tsuda Sayaka Kaino Hisashi Kokubo Shin-Ichiro Imabayashi Masayoshi Watanabe 《Colloids and surfaces. B, Biointerfaces》2007,56(1-2):255-Optics
Redox properties of phenothiazine-labeled poly(ethyl glycidy ether)-block-poly(ethylene oxide) (PT-EGEn-b-EOm) are reversibly changed by core-shell micelle formation. In the temperature range higher than the critical micellization temperature (cmt), the anodic potential of PT group positively shifts and concomitantly its anodic current decrease, or levels off compared to those of the reference polymer PT-EOm without the thermo-responsive EGEn segment. The former alteration is caused by incorporation of hydrophobic PT groups into a core of the micelle and the latter by the decrease in the diffusion coefficient of PT groups due to formation of the core-shell micelles. The cmt value and the temperature-dependent alteration in the redox properties strongly depend on the polymer structure, especially the length of thermo-responsive EGEn segment. The electrochemically determined hydrodynamic radii of the polymer aggregates seem to be overestimated, compared to the values reported for the aggregates of other thermo-responsive polymers with similar molecular weights, implying the presence of electrochemically inactive PT groups in the copolymers having longer thermo-responsive segments. 相似文献
47.
We propose a sinusoidal wavelength-scanning interferometer for measuring thickness and surface profile of a thin film. The interference signal contains phase modulation amplitude Z and phase $aL which are related to the positions and profiles of the reflecting surfaces, respectively. By reducing the difference between the detected signal and the estimated signal using the multidimensional nonlinear least-squares algorithm, we estimate values of Z and $aL. Experimental results show that the front and rear surfaces of a silica glass plate of 20 $mUm-thickness could be measured with an error less than 10 nm. 相似文献
48.
We theoretically investigated laser trimming to adjust grating offset in phase-shifted fiber grating coupler (FGC) for all-optical switching application. It was clarified that the trimming made the extinction ratio higher in all-optical FGC switch. 相似文献
49.
50.
Sonoko Kikuchi Kazuteru Kawauchi Sadatsugu Ooki Masaru Kurosawa Hisashi Honjho Teruo Yagishita 《Analytical sciences》2004,20(8):1111-1112
Using Raman spectroscopy without any preparation, we analyzed the brominated flame retardant, polybromodiphenyl ethers (PBDEs), which has been prohibited by the European Union. The typical Raman bands of PBDEs, which are clearly different from those of other brominated flame retardants, are from 100 to 300 cm(-1). In our analysis, the detection limit was about 100 ppm, and the analysis took about 1 min, whereas the usual method of solvent extraction using gas chromatography/mass spectroscopy takes 50 h. 相似文献